That is a question that often comes up at this time of year, and understandably so. Though classified by the DOT as smokeless propellants, most muzzleloaders can be safely fired with black powder, Pyrodex, Triple Seven, Black Mag3, Pyrodex pellets, and Triple Seven Pellets. Only the Savage 10ML-II was designed to be used with all of these propellants, just like other muzzleloaders, plus certain recommended nitrocellulose (smokeless) powders. Smokeless powders are non-corrosive, offer less recoil, and leave very little residue. Here is a quick look at the basics.

Black powder is an old propellant, formed from a blend of natural ingredients: sulfur, potassium nitrate, and charcoal. Classified as an explosive, few muzzleloaders use true black powder these days because of limited availability. The energy produced by black powder in small arms use varies by manufacturer. "Swiss" black powder, for example, is considered a hotter propellant than "Goex" brand.

Black powder, Pyrodex, Black Mag3, and Triple Seven loose powder are all in the category of deflagrating powders. "Deflagrating" is just a fancy way of saying "fast-burning." These powders burn just as fast as they can as long as they can. Their grain size controls the burn rate. FFFF black powder is very, very easy to ignite; that is why the common application is as pan powder for flintlocks. FFF black powder is used often in .45 caliber or smaller bore muzzleloaders and sidelocks, FF is the standard for .50 caliber inline muzzleloaders. The "F" designation is just the screen size used in manufacture and the resultant grain size (coarseness).

In black powder the fuel is carbon; we are just burning charcoal. Black powder is horribly inefficient, as only about 50% of its mass turns into gas. The rest is solid residue that is forced out the muzzle as white smoke or left in the bore as corrosive fouling crud.

Pyrodex is the most common "black powder substitute." It is really the only synthetic black powder "performance" substitute in common use. By performance substitute, I refer to a charge of loose powder measure by volume. A 100 grain volumetric charge of Pyrodex RS (Rifle/Shotgun) is very close in performance to Goex FFg black powder.

There are differences, though, and this is where things get a bit convoluted. Pyrodex is bulkier, another way of saying "less dense." By weight, it is more powerful than Goex black powder. But, the traditional method of measuring black powder is indeed by volume, so in that sense it is a black powder performance substitute.

By actual weight, it is not the same. 100 grains measured by volume of Goex FFg is about 101.3 grains by weight. 100 grains measured by volume of Pyrodex RS is about 72.5 grains by weight. Pyrodex is where confusion can start to set in, as the standard "F" designations of powder coarseness start to go out the window.

Pyrodex "Select," formulated for use in muzzleloading rifles, is touted as an "extremely consistent" grade of Pyrodex, and has the largest grain size of them all. It is even farther away from black powder by actual weight; 100 grains volumetric equals about 63.9 grains by actual weight.

Pyrodex, though man-made and with a variety of additives, still has sulfur in it and is corrosive. It is classified as a smokeless powder by the DOT, and bears little resemblance to traditional black powder in actual weight or grain size. It is a bit harder to ignite than black powder, and is safer to handle, use, and store due to this fact. It is also not as impact-sensitive as is true black powder. Pyrodex is not classified as an explosive as is black powder, and is sold at many chain stores due to this fact.

Triple Seven, Black Mag3, and Goex Clear Shot get us into an area where the muzzleloading industry has drifted into double-talk, sidestepping, and confusion. These propellants have nothing in common with true black powder at all; chemically, neither sulfur nor charcoal is present. They are still carbon-burning propellants, though, of the deflagrating (fast-burning) type. They are measured volumetrically, but only Goex Clear Shot can be considered a black powder performance substitute.

Triple Seven and Black Mag3 are far hotter (or more energetic) than good old black powder, and produce higher velocities and pressures. Still burning carbon, the carbon-based fuel burned here is from the sugar family, not from wood (charcoal). These propellants are actually far more modern than nitrocellulose based powders. Triple Seven and Black Mag3 only become available in the 21st Century.

Referring to Triple Seven and Black Mag3, the only thing that they have in common with black powder is they can be volumetrically measured with old black powder measures. They are not as corrosive as black powder (Black Mag3 claims to be non-corrosive), have little in common chemically, and produce more pressure, heat, and velocity than black powder. They are considered smokeless powder by the DOT, and should be used with caution in older muzzleloaders, as there is no way that 100 grains volumetric charge of Triple Seven or Black Mag3 can be considered "the same" as traditional black powder. They are still relatively inefficient propellants, leaving behind close to 50% of their mass as non-combusted, solid residue.

Referring to Triple Seven, that 50% unburned material is substantially less fouling than black powder for the simple reason that a 100 grain volumetric charge of Triple Seven, though it produces more energy than black powder, is far less by actual weight. More directly stated, you still have about 50% of the garbage left, but you start with less garbage to burn in the first place.

Pyrodex and Triple Seven pellets are the area where the snake oil sales pitch starts to sizzle. Sold as black powder equivalents of "pelletized powder," they have nothing to do with traditional black powder. The pelletized powder lingo is wishful thinking, as pellets are just pellets. This type of tortured language adds more confusion to the mix. If you take two tablets of aspirin and call me in the morning, you have taken two aspirin tablets, not "tabletized acetylsalicylic acid." Sometimes pellets are just pellets, ask any rabbit, and a cigar is just a cigar. Let's talk about what they really are, and what they do.

Pyrodex pellets are a sophisticated rocket fuel type propellant, more related to an Estes rocket engine than black powder. They consist of a black igniter portion on one side of the base; although called an "ignition accelerant," this is nothing more than good old black powder. They are, of course, not volumetrically measured, and they do not burn at all like loose powder. A Pyrodex pellet burns progressively down the bore, from the base in, from the outside in, and--due to the hole in the center--from the inside out.

Though not recommended by Hodgdon, most inline manufacturers currently allow and promote the use of "three pellet loads" for velocities far in excess of what loose black powder or Pyrodex can possibly achieve. How fast? One load out of the 2004 Knight catalog shows a muzzle velocity of 2417 fps, another is 2639 fps! These velocities can actually be bettered in a longer barreled gun, like the Thompson/Center Omega.

Triple Seven pellets, used in three-pellet configuration, actually produce a bit more muzzle velocity. Where Pyrodex pellets are pressed into shape from black powder and Pyrodex RS, Triple Seven pellets are made from straight Triple Seven, and are harder to ignite. For what it is worth, I've personally found Pyrodex pellet loads to be more consistent, and more accurate.

A word of caution is in order. Hodgdon does not condone the use of more than 100 grains of their Pyrodex or Triple Seven pellets in .45 or .50 caliber muzzleloaders, and they clearly, loudly proclaim that warning with every box of pellets sold. Several people have asked, "What pressures do three pellets produce?" Well, there is no finite answer. Much is necessarily contingent on projectile weight, type, and caliber of rifle.

I shoot a few flaming pellets into the air on the 4^th of July. The kids get a kick out of it, but as there is no projectile there is little pressure. Lyman Ballistic Laboratories has published three Pyrodex pellet-powered saboted bullet loads that develop 27,000 psi out of a 22" test barrel; Triple Seven pellets can produce more pressure than that.

Not all inline muzzleloaders have been tested with Triple Seven pellets, and it is a matter of public record that the casual take "three pellets and call me in the morning" approach can lead to an immediate trip to the emergency room. There are a few makes and models of inline muzzleloaders that have been extensively tested with three pellet loads, and I'll mention them right here: current production Knight Disc Rifles, Thompson Omega and Encore rifles, and the Savage 10ML-II.

Smokeless Powder, the original black powder substitute, became commercially available in the last decade of the 19th Century. As you've read above, the path to "black powder substitutes" is a convoluted, twisty one. What is called a "black powder substitute" has very little to do with the actual and factual, and a lot more to do with who has what to sell.

Only the Savage 10ML-II has been proven safe with nitrocellulose based smokeless powder, as opposed to solid fuel or deflagrating style DOT classified smokeless black powder substitutes like Triple 7 or Black Mag3 mentioned above. Folks are a bit confused about smokeless powder use in the Savage 10ML-II, but not nearly as bewildered as they are about the black powder / pellet / synthetic black powder substitute mess already described.